A Novel Equation of State: Determination and Validation for Dyes and Drugs Solubility Calculations in Supercritical Carbon Dioxide

Authors

  • Milad Asgarpour Khansary
    Affiliation
    University of Tehran
  • Ahmad Hallaji Sani
  • Hossein Shahbeig
  • Amin Arif
  • Hadi Dalirsefat
  • Mohammad Ali Salehi
https://doi.org/10.3311/PPch.7436

Abstract

Based on Pitzer correlations for the compressibility factor and virial equation of state, a new equation of state has been developed in this study, which is a function of total number of atoms present in the solute molecule, normal boiling point temperature and reduced temperature. Thirty dyes and sixty drugs solubility data, 2417 data points, have been collected from literature and compared with the Peng-Robinson EOS plus the two adjustable parameters van der Waals mixing rules, and the new proposed EOS. As the results show, the proposed EOS presents more accurate predictions for solubility data in Supercritical Carbon Dioxide.

Keywords:

Carbon dioxide, Phase Equilibria, State equation, Supercritical fluid, Thermodynamics Process, Solubility

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Published Online

2014-07-31

How to Cite

Asgarpour Khansary, M., Hallaji Sani, A., Shahbeig, H., Arif, A., Dalirsefat, H., Salehi, M. A. “A Novel Equation of State: Determination and Validation for Dyes and Drugs Solubility Calculations in Supercritical Carbon Dioxide”, Periodica Polytechnica Chemical Engineering, 58(2), pp. 179–194, 2014. https://doi.org/10.3311/PPch.7436

Issue

Vol. 58 No. 2 (2014)

Section

Articles